Side‐on Coordination in Isostructural Nitrous Oxide and Carbon Dioxide Complexes of Nickel
Year of publication
2021
Authors
Puerta Lombardi, Braulio Michele; Gendy, Chris; Gelfand, Benjamin S.; Bernard, Guy M.; Wasylishen, Roderick E.; Tuononen, Heikki M.; Roesler, Roland
Abstract
A nickel complex incorporating an N2O ligand with a rare η2‐N,N’‐coordination mode was isolated and characterized by X‐ray crystallography, as well as by IR and solid‐state NMR augmented by 15N‐labeling experiments. The isoelectronic nickel CO2 complex reported for comparison features a very similar solid‐state structure. Computational studies revealed that η2‐N2O binds to nickel slightly stronger than η2‐CO2 in this case, and comparably to or slightly stronger than η2‐CO2 to transition metals in general. Comparable transition state energies for the formation of isomeric η2‐N,N’‐ and η2‐N,O‐complexes, and a negligible activation barrier for the decomposition of the latter likely account for the limited stability of the N2O complex.
Show moreOrganizations and authors
Publication type
Publication format
Article
Parent publication type
Journal
Article type
Original article
Audience
ScientificPeer-reviewed
Peer-ReviewedMINEDU's publication type classification code
A1 Journal article (refereed), original researchPublication channel information
Journal
Publisher
Volume
60
Issue
13
Pages
7077-7081
ISSN
Publication forum
Publication forum level
3
Open access
Open access in the publisher’s service
Yes
Open access of publication channel
Partially open publication channel
Self-archived
Yes
Article processing fee (EUR)
4960
Year of payment for the open publication fee
2020
Other information
Fields of science
Chemical sciences
Keywords
[object Object],[object Object],[object Object],[object Object]
Publication country
Germany
Internationality of the publisher
International
Language
English
International co-publication
Yes
Co-publication with a company
No
DOI
10.1002/anie.202011301
The publication is included in the Ministry of Education and Culture’s Publication data collection
Yes