Effect of different co-solvents on biodiesel production from various low-cost feedstocks using Sr–Al double oxides
Year of publication
2020
Authors
Ambat, Indu; Srivastava, Varsha; Iftekhar, Sidra; Haapaniemi, Esa; Sillanpää, Mika
Abstract
The main objective of the present paper comprises the investigation of biodiesel production from low-cost feedstock such as lard oil and waste cooking oil (WCO) using Sr–Al double oxides. Nanocatalyst was characterised FTIR, XRD, SEM, TEM, BET and XPS. The Sr:Al with 3:1 M ratio showed the best catalytic activity in the conversion of both oils to fatty acid methyl ester. The effect of acetone and tetrahydrofuran (THF) as a co-solvent for transesterification were compared and the best result was obtained with 5% THF. The mutual effect of the nanocatalyst and co-solvent on biodiesel production was investigated. The characterisation of biodiesel synthesised from lard oil and WCO was performed with GC-MS, 1H and 13C NMR. Moreover, the optimum reaction parameters for transesterification reaction was analysed and the yield was determined by 1H NMR. The maximum yield of 99.7% and 99.4% of lard oil methyl ester and WCO biodiesel were observed with a 0.9 wt% catalyst amount, 1:5.5 oil to methanol ratio in a reaction time of 45 min at 50 °C and 60 °C, respectively. The properties of biodiesel from lard oil and WCO were determined by the EN 14214 method. The regeneration, characterisation and reusability of regenerated catalyst was observed.
Show moreOrganizations and authors
Publication type
Publication format
Article
Parent publication type
Journal
Article type
Original article
Audience
ScientificPeer-reviewed
Peer-ReviewedMINEDU's publication type classification code
A1 Journal article (refereed), original researchPublication channel information
Journal
Publisher
Volume
146
Pages
2158-2169
ISSN
Publication forum
Publication forum level
2
Open access
Open access in the publisher’s service
No
Self-archived
Yes
Other information
Fields of science
Chemical sciences; Chemical engineering; Environmental engineering
Keywords
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Publication country
United Kingdom
Internationality of the publisher
International
Language
English
International co-publication
No
Co-publication with a company
No
DOI
10.1016/j.renene.2019.08.061
The publication is included in the Ministry of Education and Culture’s Publication data collection
Yes