Sulfate-induced large amplitude conformational change in a Solomon link
Year of publication
2023
Authors
Do, Cuong Dat; Pál, Dávid; Belyaev, Andrey; Pupier, Marion; Kiesilä, Anniina; Kalenius, Elina; Galmés, Bartomeu; Frontera, Antonio; Poblador-Bahamonde, Amalia; Cougnon, Fabien B. L.
Abstract
A doubly-interlocked [2]catenane – or Solomon link – undergoes a complex conformational change upon addition of sulfate in methanol. This transformation generates a single pocket where two SO42− anions bind through multiple hydrogen bonds and electrostatic interactions. Despite the close proximity of the two anions, binding is highly cooperative.
Show moreOrganizations and authors
Publication type
Publication format
Article
Parent publication type
Journal
Article type
Original article
Audience
ScientificPeer-reviewed
Peer-ReviewedMINEDU's publication type classification code
A1 Journal article (refereed), original researchPublication channel information
Journal/Series
Publisher
Volume
59
Issue
87
Pages
13010-13013
ISSN
Publication forum
Publication forum level
2
Open access
Open access in the publisher’s service
Yes
Open access of publication channel
Partially open publication channel
Self-archived
Yes
Other information
Fields of science
Chemical sciences
Keywords
[object Object],[object Object],[object Object],[object Object]
Publication country
United Kingdom
Internationality of the publisher
International
Language
English
International co-publication
Yes
Co-publication with a company
No
DOI
10.1039/d3cc04555b
The publication is included in the Ministry of Education and Culture’s Publication data collection
Yes